dc.contributor.author |
Thackeray, MM
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dc.contributor.author |
De Kock, A
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dc.contributor.author |
David, WIF
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dc.date.accessioned |
2007-06-29T08:51:35Z |
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dc.date.available |
2007-06-29T08:51:35Z |
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dc.date.issued |
1993-10 |
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dc.identifier.citation |
Thackeray, MM, De Kock, A and David, WIF. 1993. Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system. Materials Research Bulletin, vol. 28(10), pp 1041-1049 |
en |
dc.identifier.issn |
0025-5408 |
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dc.identifier.uri |
http://hdl.handle.net/10204/783
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dc.description |
Copyright: Pergamon Press Ltd |
en |
dc.description.abstract |
Lithium-manganese-oxides prepared at moderate temperatures are under investigation as insertion electrodes for rechargeable lithium batteries. The structures of two defect-spinel compounds synthesized by the reaction of MnCO3 and Li2CO3 at 400°C are reported. The cation distributions in the structures were determined by neutron-diffraction to be {Li.85.15}8a [Mn1.74Li.26]16dO4 and {Li.87.13}8a [Mn1.71Li.29]16dO4, where 8a and 16d refer to the tetrahedral and octahedral sites of the prototypic spinel space group Fd3m, respectively. The structures are discussed in relation to the spinel system Li2O MnO2 (y equal or greater than 2.5). |
en |
dc.language.iso |
en |
en |
dc.publisher |
Pergamon Press Ltd |
en |
dc.subject |
Lithium |
en |
dc.subject |
Manganese |
en |
dc.subject |
Spinels |
en |
dc.subject |
Oxides |
en |
dc.title |
Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system |
en |
dc.type |
Article |
en |
dc.identifier.apacitation |
Thackeray, M., De Kock, A., & David, W. (1993). Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system. http://hdl.handle.net/10204/783 |
en_ZA |
dc.identifier.chicagocitation |
Thackeray, MM, A De Kock, and WIF David "Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system." (1993) http://hdl.handle.net/10204/783 |
en_ZA |
dc.identifier.vancouvercitation |
Thackeray M, De Kock A, David W. Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system. 1993; http://hdl.handle.net/10204/783. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Thackeray, MM
AU - De Kock, A
AU - David, WIF
AB - Lithium-manganese-oxides prepared at moderate temperatures are under investigation as insertion electrodes for rechargeable lithium batteries. The structures of two defect-spinel compounds synthesized by the reaction of MnCO3 and Li2CO3 at 400°C are reported. The cation distributions in the structures were determined by neutron-diffraction to be {Li.85.15}8a [Mn1.74Li.26]16dO4 and {Li.87.13}8a [Mn1.71Li.29]16dO4, where 8a and 16d refer to the tetrahedral and octahedral sites of the prototypic spinel space group Fd3m, respectively. The structures are discussed in relation to the spinel system Li2O MnO2 (y equal or greater than 2.5).
DA - 1993-10
DB - ResearchSpace
DP - CSIR
KW - Lithium
KW - Manganese
KW - Spinels
KW - Oxides
LK - https://researchspace.csir.co.za
PY - 1993
SM - 0025-5408
T1 - Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system
TI - Synthesis and structural characterization of defect spinels in the lithium-manganese-oxide system
UR - http://hdl.handle.net/10204/783
ER -
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en_ZA |