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Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst

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dc.contributor.author Makgwane, Peter R
dc.contributor.author Ray, SS
dc.date.accessioned 2014-09-22T13:43:11Z
dc.date.available 2014-09-22T13:43:11Z
dc.date.issued 2014-09
dc.identifier.citation Makgwane, P.R and Ray, S.S. 2014. Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. Catalysis Communications, vol. 54(5), pp 118-123 en_US
dc.identifier.issn 1566-7367
dc.identifier.uri http://ac.els-cdn.com/S156673671400212X/1-s2.0-S156673671400212X-main.pdf?_tid=1813d16c-3fe4-11e4-bf03-00000aacb35f&acdnat=1411121141_37c250b8b1098cb00f4ea110e1a684c5
dc.identifier.uri http://hdl.handle.net/10204/7682
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S156673671400212X
dc.identifier.uri https://doi.org/10.1016/j.catcom.2014.05.031
dc.description Copyright: 2014 Elsevier. This is an ABSTRACT ONLY. The definitive version is published in Catalysis Communications, vol. 54(5), pp 118-123 en_US
dc.description.abstract An efficient room temperature catalyzed oxidation of cyclohexane to cyclohexanone (K) and cyclohexanol (A) was achieved over hetero-mixed tungsten–vanadia (WO(sub3)/V(sub2)O(sub5)) using H(sub2)O(sub2) oxidant. WO(sub3)/V(sub2)O(sub5) exhibited high catalytic activity to initiate the free-radical oxyfunctionalization of cyclohexane to afford up to 90% conversions within 6 h. The KA selectivity was found to depend on reaction time and the amount of catalyst. The WO(sub3)/V(sub2)O(sub5) catalyst was highly recyclable with consistent catalytic activity. en_US
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.relation.ispartofseries Workflow;13368
dc.subject Vanadium en_US
dc.subject Tungsten en_US
dc.subject Cyclohexan en_US
dc.subject Oxidation en_US
dc.subject Hetero-mixed en_US
dc.subject Nanostructured en_US
dc.title Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst en_US
dc.type Article en_US
dc.identifier.apacitation Makgwane, P. R., & Ray, S. (2014). Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. http://hdl.handle.net/10204/7682 en_ZA
dc.identifier.chicagocitation Makgwane, Peter R, and SS Ray "Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst." (2014) http://hdl.handle.net/10204/7682 en_ZA
dc.identifier.vancouvercitation Makgwane PR, Ray S. Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst. 2014; http://hdl.handle.net/10204/7682. en_ZA
dc.identifier.ris TY - Article AU - Makgwane, Peter R AU - Ray, SS AB - An efficient room temperature catalyzed oxidation of cyclohexane to cyclohexanone (K) and cyclohexanol (A) was achieved over hetero-mixed tungsten–vanadia (WO(sub3)/V(sub2)O(sub5)) using H(sub2)O(sub2) oxidant. WO(sub3)/V(sub2)O(sub5) exhibited high catalytic activity to initiate the free-radical oxyfunctionalization of cyclohexane to afford up to 90% conversions within 6 h. The KA selectivity was found to depend on reaction time and the amount of catalyst. The WO(sub3)/V(sub2)O(sub5) catalyst was highly recyclable with consistent catalytic activity. DA - 2014-09 DB - ResearchSpace DP - CSIR KW - Vanadium KW - Tungsten KW - Cyclohexan KW - Oxidation KW - Hetero-mixed KW - Nanostructured LK - https://researchspace.csir.co.za PY - 2014 SM - 1566-7367 T1 - Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst TI - Efficient room temperature oxidation of cyclohexane over highly active hetero-mixed WO3/V2O5 oxide catalyst UR - http://hdl.handle.net/10204/7682 ER - en_ZA


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