Zirconium-based metal–organic framework (Zr-MOF) was synthesized using a microwave-assisted modulated method in a short reaction time of 5 min. The Zr-MOF material was highly crystalline with well-defined octahedral shaped crystals, and it exhibited comparable hydrogen storage capacity to Zr-MOF of similar specific surface area synthesized using conventional methods with much longer synthesis time.
Reference:
Ren, J., Segakweng, T., Langmi, H.W., Musyoka, N.M., North, B.C., Mathe, M. and Bessarabov, D. 2014. Microwave-assisted modulated synthesis of zirconium-based metal-organic framework (Zr-MOF) for hydrogen storage applications. International Journal of Materials Research, vol. 105(5), pp 516-519
Ren, J., Segakweng, T., Langmi, H. W., Musyoka, N. M., North, B. C., Mathe, M. K., & Bessarabov, D. (2014). Microwave-assisted modulated synthesis of zirconium-based metal–organic framework (Zr-MOF) for hydrogen storage applications. http://hdl.handle.net/10204/7587
Ren, Jianwei, T Segakweng, Henrietta W Langmi, Nicholas M Musyoka, Brian C North, Mahlanyane K Mathe, and D Bessarabov "Microwave-assisted modulated synthesis of zirconium-based metal–organic framework (Zr-MOF) for hydrogen storage applications." (2014) http://hdl.handle.net/10204/7587
Ren J, Segakweng T, Langmi HW, Musyoka NM, North BC, Mathe MK, et al. Microwave-assisted modulated synthesis of zirconium-based metal–organic framework (Zr-MOF) for hydrogen storage applications. 2014; http://hdl.handle.net/10204/7587.