dc.contributor.author |
Ren, Jianwei
|
|
dc.contributor.author |
Rogers, DEC
|
|
dc.contributor.author |
Segakweng, T
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|
dc.contributor.author |
Langmi, Henrietta W
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|
dc.contributor.author |
North, Brian C
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|
dc.contributor.author |
Mathe, Mahlanyane K
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|
dc.contributor.author |
Bessarabov, D
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|
dc.date.accessioned |
2014-05-13T07:24:26Z |
|
dc.date.available |
2014-05-13T07:24:26Z |
|
dc.date.issued |
2013 |
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dc.identifier.citation |
Ren, J, Rogers, D.E.C, Segakweng, T, Langmi, H.W, North, B.C, Mathe, M and Bessarabov, D. 2013. Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5). International Journal of Materials Research, vol. 105(1), pp 89-93 |
en_US |
dc.identifier.issn |
1862-5282 |
|
dc.identifier.uri |
http://www.hanser-elibrary.com/doi/abs/10.3139/146.110994
|
|
dc.identifier.uri |
http://hdl.handle.net/10204/7400
|
|
dc.identifier.uri |
https://doi.org/10.3139/146.110994
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|
dc.description |
Copyright: 2013 Carl Hanser Verlag. This is an ABSTRACT ONLY. The definitive version is published in International Journal of Materials Research, vol. 105(1), pp 89-93 |
en_US |
dc.description.abstract |
A simple thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) is reported. Phase crystallinity, pore characteristics and hydrogen storage capacities of the resulting crystals were investigated. It is shown that the structural transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) could be induced by simply employing the optimal thermal treatment conditions of 200 °C for 48 h in open air. The resultant relatively lower specific surface area of MOF-5 crystals compared to MOF-69c was in agreement with the increased pore diameter and decreased hydrogen storage capacity at 1 bar and 77 K. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Carl Hanser Verlag |
en_US |
dc.relation.ispartofseries |
Workflow;12079 |
|
dc.subject |
Structural transition |
en_US |
dc.subject |
Hydrogen adsorption |
en_US |
dc.subject |
MOF-69c |
en_US |
dc.subject |
MOF-5 |
en_US |
dc.title |
Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Ren, J., Rogers, D., Segakweng, T., Langmi, H. W., North, B. C., Mathe, M. K., & Bessarabov, D. (2013). Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5). http://hdl.handle.net/10204/7400 |
en_ZA |
dc.identifier.chicagocitation |
Ren, Jianwei, DEC Rogers, T Segakweng, Henrietta W Langmi, Brian C North, Mahlanyane K Mathe, and D Bessarabov "Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5)." (2013) http://hdl.handle.net/10204/7400 |
en_ZA |
dc.identifier.vancouvercitation |
Ren J, Rogers D, Segakweng T, Langmi HW, North BC, Mathe MK, et al. Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5). 2013; http://hdl.handle.net/10204/7400. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Ren, Jianwei
AU - Rogers, DEC
AU - Segakweng, T
AU - Langmi, Henrietta W
AU - North, Brian C
AU - Mathe, Mahlanyane K
AU - Bessarabov, D
AB - A simple thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) is reported. Phase crystallinity, pore characteristics and hydrogen storage capacities of the resulting crystals were investigated. It is shown that the structural transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) could be induced by simply employing the optimal thermal treatment conditions of 200 °C for 48 h in open air. The resultant relatively lower specific surface area of MOF-5 crystals compared to MOF-69c was in agreement with the increased pore diameter and decreased hydrogen storage capacity at 1 bar and 77 K.
DA - 2013
DB - ResearchSpace
DP - CSIR
KW - Structural transition
KW - Hydrogen adsorption
KW - MOF-69c
KW - MOF-5
LK - https://researchspace.csir.co.za
PY - 2013
SM - 1862-5282
T1 - Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5)
TI - Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5)
UR - http://hdl.handle.net/10204/7400
ER -
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en_ZA |