dc.contributor.author |
Pelly, SC
|
en_US |
dc.contributor.author |
Parkinson, CJ
|
en_US |
dc.contributor.author |
Van Otterlo, WAL
|
en_US |
dc.contributor.author |
De Koning, CB
|
en_US |
dc.date.accessioned |
2007-03-26T09:43:46Z |
en_US |
dc.date.accessioned |
2007-06-07T10:06:09Z |
|
dc.date.available |
2007-03-26T09:43:46Z |
en_US |
dc.date.available |
2007-06-07T10:06:09Z |
|
dc.date.copyright |
|
en_US |
dc.date.issued |
2005-12-09 |
en_US |
dc.identifier.citation |
Pelly, SC, et al. 2005. Metathesis reactions for the synthesis of ring-fused carbazoles. Journal of Organic Chemistry, vol. 70(25), pp 10474-10481 |
en_US |
dc.identifier.issn |
0022-3263 |
en_US |
dc.identifier.uri |
http://hdl.handle.net/10204/2040
|
en_US |
dc.identifier.uri |
http://hdl.handle.net/10204/2040
|
|
dc.description.abstract |
The metathesis reaction is used as a key step for the synthesis of the indolo [2,3-a] carbazole core of rebeccamycin 13 and the sulfur analog of furostifoline 21. Using the same methodology for the attempted synthesis of furostifoline, the authors unexpectedly formed tert-butyl-2a-methyl-1,2,2a,10c-tetrahydro-6H-cyclobuta[c]furo[3,2-a]carbazole-6-carboxylate 26 from the unstable diene, tert-butyl 2-(2-isopropenyl-3-furyl)-3-vinyl-1H-indole-1-carboxylate 25, presumably via a spontaneous pi(8) electrocyclization reaction. |
en_US |
dc.format.extent |
175486 bytes |
en_US |
dc.format.mimetype |
application/pdf |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.rights |
Copyright: 2005 American Chemical Society |
en_US |
dc.source |
|
en_US |
dc.subject |
Metathesis reactions |
en_US |
dc.subject |
Carbazoles |
en_US |
dc.subject |
Furostifoline synthesis |
en_US |
dc.subject |
Tert butyl methyl |
en_US |
dc.subject |
Organic chemistry |
en_US |
dc.title |
Metathesis reactions for the synthesis of ring-fused carbazoles |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Pelly, S., Parkinson, C., Van Otterlo, W., & De Koning, C. (2005). Metathesis reactions for the synthesis of ring-fused carbazoles. http://hdl.handle.net/10204/2040 |
en_ZA |
dc.identifier.chicagocitation |
Pelly, SC, CJ Parkinson, WAL Van Otterlo, and CB De Koning "Metathesis reactions for the synthesis of ring-fused carbazoles." (2005) http://hdl.handle.net/10204/2040 |
en_ZA |
dc.identifier.vancouvercitation |
Pelly S, Parkinson C, Van Otterlo W, De Koning C. Metathesis reactions for the synthesis of ring-fused carbazoles. 2005; http://hdl.handle.net/10204/2040. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Pelly, SC
AU - Parkinson, CJ
AU - Van Otterlo, WAL
AU - De Koning, CB
AB - The metathesis reaction is used as a key step for the synthesis of the indolo [2,3-a] carbazole core of rebeccamycin 13 and the sulfur analog of furostifoline 21. Using the same methodology for the attempted synthesis of furostifoline, the authors unexpectedly formed tert-butyl-2a-methyl-1,2,2a,10c-tetrahydro-6H-cyclobuta[c]furo[3,2-a]carbazole-6-carboxylate 26 from the unstable diene, tert-butyl 2-(2-isopropenyl-3-furyl)-3-vinyl-1H-indole-1-carboxylate 25, presumably via a spontaneous pi(8) electrocyclization reaction.
DA - 2005-12-09
DB - ResearchSpace
DP - CSIR
KW - Metathesis reactions
KW - Carbazoles
KW - Furostifoline synthesis
KW - Tert butyl methyl
KW - Organic chemistry
LK - https://researchspace.csir.co.za
PY - 2005
SM - 0022-3263
T1 - Metathesis reactions for the synthesis of ring-fused carbazoles
TI - Metathesis reactions for the synthesis of ring-fused carbazoles
UR - http://hdl.handle.net/10204/2040
ER -
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en_ZA |