ResearchSpace

Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system

Show simple item record

dc.contributor.author Thackeray, MM en_US
dc.contributor.author De Kock, A en_US
dc.contributor.author David, WIF en_US
dc.date.accessioned 2007-03-14T13:26:10Z en_US
dc.date.accessioned 2007-06-07T10:04:25Z
dc.date.available 2007-03-14T13:26:10Z en_US
dc.date.available 2007-06-07T10:04:25Z
dc.date.issued 1993-10 en_US
dc.identifier.citation Thackeray, MM, et al. 1993. Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system. Material Research Bulletin, vol 28(10), pp 1041-1049 en_US
dc.identifier.issn 0025-5408 en_US
dc.identifier.uri http://hdl.handle.net/10204/1937 en_US
dc.identifier.uri http://hdl.handle.net/10204/1937
dc.description.abstract Lithium-manganese-oxides prepared at moderate temperatures are under investigation as insertion electrodes for rechargeable lithium batteries. The structures of two defect-spinel compounds synthesised by the reaction of MnCO3 and Li2CO3 at 400-degrees-C are reported. The cation distributions in the structures were determined by neutron-diffraction to be {Li.85 square .15}8a [Mn1.74Li.26]16dO4 and (Li.87 square .13}8a [Mn1.71Li.29]16dO4, where 8a and 16d refer to the tetrahedral and octahedral sites of the prototypic spinel space group Fd3m, respectively. The structures are discussed in relation to the spinel system Li2O.yMnO2 (y greater-than-or-equal-to 2.5). en_US
dc.format.extent 468154 bytes en_US
dc.format.mimetype application/pdf en_US
dc.language.iso en en_US
dc.publisher Pergamon-Elsevier Science Ltd en_US
dc.rights Copyright: 1993 Pergamon-Elsevier Science Ltd en_US
dc.subject Spinels en_US
dc.subject Oxides en_US
dc.subject Manganese en_US
dc.subject Lithium en_US
dc.title Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system en_US
dc.type Article en_US
dc.identifier.apacitation Thackeray, M., De Kock, A., & David, W. (1993). Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system. http://hdl.handle.net/10204/1937 en_ZA
dc.identifier.chicagocitation Thackeray, MM, A De Kock, and WIF David "Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system." (1993) http://hdl.handle.net/10204/1937 en_ZA
dc.identifier.vancouvercitation Thackeray M, De Kock A, David W. Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system. 1993; http://hdl.handle.net/10204/1937. en_ZA
dc.identifier.ris TY - Article AU - Thackeray, MM AU - De Kock, A AU - David, WIF AB - Lithium-manganese-oxides prepared at moderate temperatures are under investigation as insertion electrodes for rechargeable lithium batteries. The structures of two defect-spinel compounds synthesised by the reaction of MnCO3 and Li2CO3 at 400-degrees-C are reported. The cation distributions in the structures were determined by neutron-diffraction to be {Li.85 square .15}8a [Mn1.74Li.26]16dO4 and (Li.87 square .13}8a [Mn1.71Li.29]16dO4, where 8a and 16d refer to the tetrahedral and octahedral sites of the prototypic spinel space group Fd3m, respectively. The structures are discussed in relation to the spinel system Li2O.yMnO2 (y greater-than-or-equal-to 2.5). DA - 1993-10 DB - ResearchSpace DP - CSIR KW - Spinels KW - Oxides KW - Manganese KW - Lithium LK - https://researchspace.csir.co.za PY - 1993 SM - 0025-5408 T1 - Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system TI - Synthesis and structural characterization of defect spinels in the Lithium-Manganese-Oxide system UR - http://hdl.handle.net/10204/1937 ER - en_ZA


Files in this item

Thumbnail
Name: thackeray_1993_2.pdf
Size: 457.1Kb
Format: PDF
View/Open

This item appears in the following Collection(s)

Show simple item record