Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical
Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical
Incorporation studies of [2-(2)H(3),2-(13)C].acetate and different [2H, 13C]-labelled mevalonolactones into verruculogen established the stereochemical course of ring C formation in fumitremorgin B, which results in the loss of stereochemical integrity of the C-22 methyl groups, and of the formation of the eight-membered peroxide ring at C-25 in verruculogen.
Reference:
Vleggaar, R, et al. 1993. Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. Journal of the Chemical Society-Chemical Communications, Issue 3, pp 274-275
Vleggaar, R., Horak, R., & Maharaj, V. (1993). Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. http://hdl.handle.net/10204/1911
Vleggaar, R, RM Horak, and VJ Maharaj "Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical." (1993) http://hdl.handle.net/10204/1911
Vleggaar R, Horak R, Maharaj V. Stereochemical course of ring formation in fumitremorgin-B and verruculogen, metabolites of pennincillim-verrucuilosum-investigation into the loss of stereochemical. 1993; http://hdl.handle.net/10204/1911.
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