dc.contributor.author |
Shyamal, S
|
|
dc.contributor.author |
Maity, Arjun
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|
dc.contributor.author |
Satpati, AK
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|
dc.contributor.author |
Bhattacharya, C
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|
dc.date.accessioned |
2019-10-09T09:21:44Z |
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dc.date.available |
2019-10-09T09:21:44Z |
|
dc.date.issued |
2019-06 |
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dc.identifier.citation |
Shyamal, S. et al. 2019. Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant. Applied Catalysis B: Environmental, vol. 246, pp. 111-119 |
en_US |
dc.identifier.issn |
0926-3373 |
|
dc.identifier.issn |
1873-3883 |
|
dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S0926337319300177
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|
dc.identifier.uri |
https://doi.org/10.1016/j.apcatb.2019.01.017
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|
dc.identifier.uri |
http://hdl.handle.net/10204/11160
|
|
dc.description |
Copyright: 2019 Elsevier. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Applied Catalysis B: Environmental, vol. 246, pp. 111-119 |
en_US |
dc.description.abstract |
A facile single step electro-synthesis is applied to develop Cu/Cu2O/Cd(OH)2 thin films from the alkaline copper sulfate solution in presence of different levels of Cd2+. Cadmium implemented a synergistic effect, in the modification of Cu2O, through the diffusion into the bulk Cu2O and formation of Cd(OH)2 buffer layer. The photoelectrochemical (PEC) performances of the optimized Cu/Cu2O/Cd(OH)2, significantly enhance the H+ reduction photocurrent to -6.1 mA/cm2 (1.5 times than that of pure Cu/Cu2O) and the solar energy conversion efficiency also improve up to 5.8%, which is 2 fold higher than the pure semiconductor. Experimental evidences, including SEM-EDX, XRD, Raman, XPS and EIS confirm that Cd modifies Cu2O through lowering the particle size with better crystallinity (accretive working surface area), minimizing resistance, increasing carrier concentration and rapid transfer of photogenerated charge carrier, resulting in suppression in electron-hole recombination, which facilitates the improved PEC performances. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsevier |
en_US |
dc.relation.ispartofseries |
Workflow;22687 |
|
dc.subject |
Carrier concentration |
en_US |
dc.subject |
Cd modified Cu2O semiconductor |
en_US |
dc.subject |
One pot electro-synthesis |
en_US |
dc.subject |
Photoelectrochemical hydrogen production |
en_US |
dc.subject |
Transit time |
en_US |
dc.title |
Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Shyamal, S., Maity, A., Satpati, A., & Bhattacharya, C. (2019). Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant. http://hdl.handle.net/10204/11160 |
en_ZA |
dc.identifier.chicagocitation |
Shyamal, S, Arjun Maity, AK Satpati, and C Bhattacharya "Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant." (2019) http://hdl.handle.net/10204/11160 |
en_ZA |
dc.identifier.vancouvercitation |
Shyamal S, Maity A, Satpati A, Bhattacharya C. Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant. 2019; http://hdl.handle.net/10204/11160. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Shyamal, S
AU - Maity, Arjun
AU - Satpati, AK
AU - Bhattacharya, C
AB - A facile single step electro-synthesis is applied to develop Cu/Cu2O/Cd(OH)2 thin films from the alkaline copper sulfate solution in presence of different levels of Cd2+. Cadmium implemented a synergistic effect, in the modification of Cu2O, through the diffusion into the bulk Cu2O and formation of Cd(OH)2 buffer layer. The photoelectrochemical (PEC) performances of the optimized Cu/Cu2O/Cd(OH)2, significantly enhance the H+ reduction photocurrent to -6.1 mA/cm2 (1.5 times than that of pure Cu/Cu2O) and the solar energy conversion efficiency also improve up to 5.8%, which is 2 fold higher than the pure semiconductor. Experimental evidences, including SEM-EDX, XRD, Raman, XPS and EIS confirm that Cd modifies Cu2O through lowering the particle size with better crystallinity (accretive working surface area), minimizing resistance, increasing carrier concentration and rapid transfer of photogenerated charge carrier, resulting in suppression in electron-hole recombination, which facilitates the improved PEC performances.
DA - 2019-06
DB - ResearchSpace
DP - CSIR
KW - Carrier concentration
KW - Cd modified Cu2O semiconductor
KW - One pot electro-synthesis
KW - Photoelectrochemical hydrogen production
KW - Transit time
LK - https://researchspace.csir.co.za
PY - 2019
SM - 0926-3373
SM - 1873-3883
T1 - Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant
TI - Amplification of PEC hydrogen production through synergistic modification of Cu2O using cadmium as buffer layer and dopant
UR - http://hdl.handle.net/10204/11160
ER -
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en_ZA |