dc.contributor.author |
Sebati, Ngwanamohuba W
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|
dc.contributor.author |
Ray, Suprakas S
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|
dc.contributor.author |
Moutloali, Richard
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|
dc.date.accessioned |
2019-09-30T07:17:05Z |
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dc.date.available |
2019-09-30T07:17:05Z |
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dc.date.issued |
2019-07 |
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dc.identifier.citation |
Sebati, N.W., Ray, S.S. & Moutloali, R. 2019. Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose. Catalysts, vol 9(8), pp. 1-19 |
en_US |
dc.identifier.issn |
2073-4344 |
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dc.identifier.uri |
https://doi.org/10.3390/catal9080656
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dc.identifier.uri |
https://www.mdpi.com/2073-4344/9/8/656
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dc.identifier.uri |
http://hdl.handle.net/10204/11141
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|
dc.description |
Copyright: 2019 Multidisciplinary Digital Publishing Institute (MDPI) |
en_US |
dc.description.abstract |
Herein, we report the synthesis of nanoporous polytriphenylamine polymers (PPTPA) by a simple one-step oxidative polymerization pathway and the materials were sulfonated with chlorosulfonic acid to introduce acidic sulfonic groups to the polymers to form solid acid catalysts (SPPTPA). Magnetic properties were added to SPPTPA catalysts by depositing Fe3O4 nanoparticles to develop (FeSPPTPA) solid acid catalysts, for performing dehydration of fructose to 5-hydroxymethylfurfural (HMF), which is regarded as a sustainable source for liquid fuels and commodity chemicals. XRD, FTIR spectroscopy, SEM, TGA, and N2 sorption techniques were used to characterize synthesized materials. The FeSPPTPA80 nanocatalyst showed superior catalytic activities in comparison to other catalysts due to the nanorods that formed after sulfonation of the PPTPA polymeric material which gave the catalyst enough catalytic centers for dehydration reaction of fructose. The recyclability tests revealed that the magnetic solid acid catalysts could be reused for four consecutive catalytic runs, which made FeSPPTPA a potential nanocatalyst for production of HMF. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Multidisciplinary Digital Publishing Institute (MDPI) |
en_US |
dc.relation.ispartofseries |
Workflow;22675 |
|
dc.subject |
Acid catalyst |
en_US |
dc.subject |
Dehydration |
en_US |
dc.subject |
Fructose |
en_US |
dc.subject |
Porous organic polymer |
en_US |
dc.subject |
5-hydroxymethylfurfural |
en_US |
dc.title |
Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Sebati, N. W., Ray, S. S., & Moutloali, R. (2019). Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose. http://hdl.handle.net/10204/11141 |
en_ZA |
dc.identifier.chicagocitation |
Sebati, Ngwanamohuba W, Suprakas S Ray, and Richard Moutloali "Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose." (2019) http://hdl.handle.net/10204/11141 |
en_ZA |
dc.identifier.vancouvercitation |
Sebati NW, Ray SS, Moutloali R. Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose. 2019; http://hdl.handle.net/10204/11141. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Sebati, Ngwanamohuba W
AU - Ray, Suprakas S
AU - Moutloali, Richard
AB - Herein, we report the synthesis of nanoporous polytriphenylamine polymers (PPTPA) by a simple one-step oxidative polymerization pathway and the materials were sulfonated with chlorosulfonic acid to introduce acidic sulfonic groups to the polymers to form solid acid catalysts (SPPTPA). Magnetic properties were added to SPPTPA catalysts by depositing Fe3O4 nanoparticles to develop (FeSPPTPA) solid acid catalysts, for performing dehydration of fructose to 5-hydroxymethylfurfural (HMF), which is regarded as a sustainable source for liquid fuels and commodity chemicals. XRD, FTIR spectroscopy, SEM, TGA, and N2 sorption techniques were used to characterize synthesized materials. The FeSPPTPA80 nanocatalyst showed superior catalytic activities in comparison to other catalysts due to the nanorods that formed after sulfonation of the PPTPA polymeric material which gave the catalyst enough catalytic centers for dehydration reaction of fructose. The recyclability tests revealed that the magnetic solid acid catalysts could be reused for four consecutive catalytic runs, which made FeSPPTPA a potential nanocatalyst for production of HMF.
DA - 2019-07
DB - ResearchSpace
DP - CSIR
KW - Acid catalyst
KW - Dehydration
KW - Fructose
KW - Porous organic polymer
KW - 5-hydroxymethylfurfural
LK - https://researchspace.csir.co.za
PY - 2019
SM - 2073-4344
T1 - Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose
TI - Synthesis of porous organic polymer-based solid-acid catalysts for 5-hydroxymethylfurfural production from fructose
UR - http://hdl.handle.net/10204/11141
ER -
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en_ZA |