dc.contributor.author |
Kumar, Neeraj
|
|
dc.contributor.author |
Fosso-Kankeu, E
|
|
dc.contributor.author |
Ray, Suprakas S
|
|
dc.date.accessioned |
2019-08-12T06:56:52Z |
|
dc.date.available |
2019-08-12T06:56:52Z |
|
dc.date.issued |
2019-05 |
|
dc.identifier.citation |
Kumar, N., Fosso-Kankeu, E. & Ray, S.S. 2019. Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems. ACS Applied Materials & Interfaces, vol. ;11, no 21, pp. 19141-19155 |
en_US |
dc.identifier.issn |
1944-8244 |
|
dc.identifier.issn |
https://doi.org/10.1021/acsami.9b03853 |
|
dc.identifier.issn |
https://pubs.acs.org/doi/10.1021/acsami.9b03853 |
|
dc.identifier.uri |
http://hdl.handle.net/10204/11069
|
|
dc.description |
Copyright: 2019. American Chemical Society. This is an abstract. The definitive version of the work is published in ACS Applied Materials & Interfaces, Vol. 11, no. 21, pp. 19141-19155 |
en_US |
dc.description.abstract |
The development of new synthesis approaches for MoS2 is necessary to achieve controlled morphologies and unique physicochemical properties that can improve its efficiency in particular applications. Herein, a facile one-step hydrothermal route is proposed to prepare controllable MoS2 micro/nanostructures with an increased interlayer using sodium diethyldithiocarbamate trihydrate as the new S source at different pH values. To investigate the morphology, chemical composition, and structure of the MoS2 micro/nanostructures, various characterization techniques were used. The obtained microrods, microspheres, and microrods with hairlike structures (denoted as MoS2-N-H) were composed of MoS2 nanosheets with increased interlayer spacing (~1.0 nm) and utilized for the removal of Pb(II) from aquatic systems. Among the structures, MoS2-N-H demonstrated the highest adsorption capacity (303.04 mg/g) for Pb(II) due to the existence of -S/–C/–N/–O-comprised functional groups on its surface, which led to strong Pb–S complexation and electrostatic attractions. The uptake of Pb(II) onto MoS2-N-H followed pseudo-second-order kinetics and Freundlich isotherm. To evaluate its practical applicability, the adsorbent was employed in real mine water analysis; it was found that MoS2-N-H could adsorb almost 100% of the Pb(II) ions in the presence of various coexisting ions. Additionally, after Pb(II) adsorption, MoS2-N-H was transformed into PbMoO4-xSx spindlelike nanostructures, which were further used for photodegradation of an antibiotic, viz., ciprofloxacin (CIP), to avoid secondary environment waste. Thus, this investigation provides an effective one-pot approach to fabricate controllable MoS2 micro/nanostructures with increased interlayer spacing for water treatment. The utility of these nanostructures in related supercapacitor/battery applications may also be envisaged because of their unique structural properties. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.relation.ispartofseries |
Workflow;22475 |
|
dc.relation.ispartofseries |
Workflow;22475 |
|
dc.subject |
Ciprofloxacin |
en_US |
dc.subject |
Lead adsorption |
en_US |
dc.subject |
MoS2 nanostructure |
en_US |
dc.subject |
Photocatalysis |
en_US |
dc.subject |
Secondary waste |
en_US |
dc.subject |
Water purification |
en_US |
dc.title |
Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Kumar, N., Fosso-Kankeu, E., & Ray, S. S. (2019). Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems. http://hdl.handle.net/10204/11069 |
en_ZA |
dc.identifier.chicagocitation |
Kumar, Neeraj, E Fosso-Kankeu, and Suprakas S Ray "Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems." (2019) http://hdl.handle.net/10204/11069 |
en_ZA |
dc.identifier.vancouvercitation |
Kumar N, Fosso-Kankeu E, Ray SS. Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems. 2019; http://hdl.handle.net/10204/11069. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Kumar, Neeraj
AU - Fosso-Kankeu, E
AU - Ray, Suprakas S
AB - The development of new synthesis approaches for MoS2 is necessary to achieve controlled morphologies and unique physicochemical properties that can improve its efficiency in particular applications. Herein, a facile one-step hydrothermal route is proposed to prepare controllable MoS2 micro/nanostructures with an increased interlayer using sodium diethyldithiocarbamate trihydrate as the new S source at different pH values. To investigate the morphology, chemical composition, and structure of the MoS2 micro/nanostructures, various characterization techniques were used. The obtained microrods, microspheres, and microrods with hairlike structures (denoted as MoS2-N-H) were composed of MoS2 nanosheets with increased interlayer spacing (~1.0 nm) and utilized for the removal of Pb(II) from aquatic systems. Among the structures, MoS2-N-H demonstrated the highest adsorption capacity (303.04 mg/g) for Pb(II) due to the existence of -S/–C/–N/–O-comprised functional groups on its surface, which led to strong Pb–S complexation and electrostatic attractions. The uptake of Pb(II) onto MoS2-N-H followed pseudo-second-order kinetics and Freundlich isotherm. To evaluate its practical applicability, the adsorbent was employed in real mine water analysis; it was found that MoS2-N-H could adsorb almost 100% of the Pb(II) ions in the presence of various coexisting ions. Additionally, after Pb(II) adsorption, MoS2-N-H was transformed into PbMoO4-xSx spindlelike nanostructures, which were further used for photodegradation of an antibiotic, viz., ciprofloxacin (CIP), to avoid secondary environment waste. Thus, this investigation provides an effective one-pot approach to fabricate controllable MoS2 micro/nanostructures with increased interlayer spacing for water treatment. The utility of these nanostructures in related supercapacitor/battery applications may also be envisaged because of their unique structural properties.
DA - 2019-05
DB - ResearchSpace
DP - CSIR
KW - Ciprofloxacin
KW - Lead adsorption
KW - MoS2 nanostructure
KW - Photocatalysis
KW - Secondary waste
KW - Water purification
LK - https://researchspace.csir.co.za
PY - 2019
SM - 1944-8244
SM - https://doi.org/10.1021/acsami.9b03853
SM - https://pubs.acs.org/doi/10.1021/acsami.9b03853
T1 - Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems
TI - Achieving Controllable MoS2 Nanostructures with Increased Interlayer Spacing for Efficient Removal of Pb(II) from Aquatic Systems
UR - http://hdl.handle.net/10204/11069
ER -
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en_ZA |