dc.contributor.author |
Botlhoko, Orebotse J
|
|
dc.contributor.author |
Ramontja, J
|
|
dc.contributor.author |
Ray, Suprakas S
|
|
dc.date.accessioned |
2018-11-08T08:17:46Z |
|
dc.date.available |
2018-11-08T08:17:46Z |
|
dc.date.issued |
2018-03 |
|
dc.identifier.citation |
Botlhoko, O.J., Ramontja, J. and Ray, S.S. 2018. Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites. Polymer, vol. 139: 188-200 |
en_US |
dc.identifier.issn |
0032-3861 |
|
dc.identifier.issn |
1873-2291 |
|
dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S0032386118301228
|
|
dc.identifier.uri |
https://doi.org/10.1016/j.polymer.2018.02.005
|
|
dc.identifier.uri |
http://hdl.handle.net/10204/10529
|
|
dc.description |
Copyright: 2018 Elsevier. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Polymer, vol. 139: 188-200 |
en_US |
dc.description.abstract |
Graphene nanosheets with relatively high surface areas and few layers were prepared by the thermal shocking of graphene oxide at 700 °C for the development of biodegradable polylactide/poly(e-caprolactone) (PLA/PCL) blend composites via a melt-blending method. A 60PLA/40PCL blend was selected as a model blend system and the effects of graphene oxide nanoplatelet incorporation (0.05–0.25 wt%) on the morphological development, thermal stability, tensile and rheological properties, and thermal and electrical conductivities were investigated. Morphological studies using transmission electron microscopy and optical microscopy indicated that the graphene oxide particles were located mainly in the minor PCL phase, where the interphase between PLA and PCL acted as a compatibilizer. In addition, characterization of the composites confirmed significant improvements in ductility, with an improved balance between the tensile modulus and strength; however, the composite containing 0.05 wt% graphene oxide exhibited a superior improvement in thermal stability and thermal conductivity compared to the other blend composites. This study therefore gives us an opportunity to design biodegradable polymer-based advanced composite materials with desirable properties by the careful selection of filler loadings, which further widens the application of PLA matrices. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsevier |
en_US |
dc.relation.ispartofseries |
Worklist;21495 |
|
dc.subject |
Morphology |
en_US |
dc.subject |
Compatibilization |
en_US |
dc.subject |
Thermal conductivity |
en_US |
dc.subject |
Electrical resistivity |
en_US |
dc.subject |
Graphene oxide |
en_US |
dc.subject |
PLA/PCL blend composite |
en_US |
dc.title |
Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites |
en_US |
dc.type |
Article |
en_US |
dc.identifier.apacitation |
Botlhoko, O. J., Ramontja, J., & Ray, S. S. (2018). Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites. http://hdl.handle.net/10204/10529 |
en_ZA |
dc.identifier.chicagocitation |
Botlhoko, Orebotse J, J Ramontja, and Suprakas S Ray "Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites." (2018) http://hdl.handle.net/10204/10529 |
en_ZA |
dc.identifier.vancouvercitation |
Botlhoko OJ, Ramontja J, Ray SS. Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites. 2018; http://hdl.handle.net/10204/10529. |
en_ZA |
dc.identifier.ris |
TY - Article
AU - Botlhoko, Orebotse J
AU - Ramontja, J
AU - Ray, Suprakas S
AB - Graphene nanosheets with relatively high surface areas and few layers were prepared by the thermal shocking of graphene oxide at 700 °C for the development of biodegradable polylactide/poly(e-caprolactone) (PLA/PCL) blend composites via a melt-blending method. A 60PLA/40PCL blend was selected as a model blend system and the effects of graphene oxide nanoplatelet incorporation (0.05–0.25 wt%) on the morphological development, thermal stability, tensile and rheological properties, and thermal and electrical conductivities were investigated. Morphological studies using transmission electron microscopy and optical microscopy indicated that the graphene oxide particles were located mainly in the minor PCL phase, where the interphase between PLA and PCL acted as a compatibilizer. In addition, characterization of the composites confirmed significant improvements in ductility, with an improved balance between the tensile modulus and strength; however, the composite containing 0.05 wt% graphene oxide exhibited a superior improvement in thermal stability and thermal conductivity compared to the other blend composites. This study therefore gives us an opportunity to design biodegradable polymer-based advanced composite materials with desirable properties by the careful selection of filler loadings, which further widens the application of PLA matrices.
DA - 2018-03
DB - ResearchSpace
DP - CSIR
KW - Morphology
KW - Compatibilization
KW - Thermal conductivity
KW - Electrical resistivity
KW - Graphene oxide
KW - PLA/PCL blend composite
LK - https://researchspace.csir.co.za
PY - 2018
SM - 0032-3861
SM - 1873-2291
T1 - Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites
TI - Morphological development and enhancement of thermal, mechanical, and electronic properties of thermally exfoliated graphene oxide-filled biodegradable polylactide/poly(e-caprolactone) blend composites
UR - http://hdl.handle.net/10204/10529
ER -
|
en_ZA |